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Phosphine and carbene azido-cations: [(L)N(3)](+) and [(L)(2)N(3)](+)

The cationic N(3)-species [(p-HC(6)F(4))(3)PN(3)](+) (1) featuring a perfluoro-arene phosphonium group serves as a N(3)(+)-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N(3)](+) and [(L)(2)N(3)](+) cations (L = phosphine, carbene) with lib...

詳細記述

保存先:
書誌詳細
出版年:Chem Sci
主要な著者: Winkelhaus, Daniel, Holthausen, Michael H., Dobrovetsky, Roman, Stephan, Douglas W.
フォーマット: Artigo
言語:Inglês
出版事項: Royal Society of Chemistry 2015
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6054069/
https://ncbi.nlm.nih.gov/pubmed/30090255
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02336j
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