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Divergent Synthesis of Natural Derivatives of (+)-Saxitoxin Including 11-Saxitoxinethanoic Acid

The bis-guanidinium toxins are a collection of natural products that display nanomolar potency against select isoforms of eukaryotic voltage-gated Na(+) ion channels. We describe a synthetic strategy that enables access to four of these poisons, including 11-saxitoxinethanoic acid, C13-acetoxy saxit...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Walker, James R., Merit, Jeffrey E., Thomas-Tran, Rhiannon, Tang, Doris T. Y., Du Bois, J.
Formato: Artigo
Idioma:Inglês
Publicado: 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6426452/
https://ncbi.nlm.nih.gov/pubmed/30488599
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201811717
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