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A stereocontrolled synthesis of (+)-saxitoxin
A concise stereoselective total synthesis of (+)-saxitoxin is described. A silver-(I)-initiated hydroamination cascade constructs the bicyclic guanidinium ion core from a propargyl-bis-guanidine. This sequence creates 2 C-N bonds, 1 C-O bond, and three rings as a single stereoisomer in a single synt...
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| Auteurs principaux: | , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2011
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3320040/ https://ncbi.nlm.nih.gov/pubmed/22098556 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2098063 |
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