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Stereocontrolled Synthesis of 2‐Fluorinated C‐Glycosides

A systematic study of the addition of C‐based nucleophiles to fluorinated lactones based on 2‐deoxy‐2‐fluoro‐d‐pyranoses is disclosed. This high yielding, α‐selective process was found to be independent on the nature or configuration [(R)‐C(sp(3))–F, (S)‐C(sp(3))–F] of the substituent at C2. Represe...

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Detalhes bibliográficos
Publicado no:European J Org Chem
Main Authors: Sadurní, Anna, Gilmour, Ryan
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6099233/
https://ncbi.nlm.nih.gov/pubmed/30147438
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201800618
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