ロード中...
Copper-catalyzed oxidative benzylic C-H cyclization via iminyl radical from intermolecular anion-radical redox relay
Base-promoted C-H cleavage without transition metals opens a practical alternative for the one based on noble metals or radical initiators. The resulting carbanion can pass through radical addition to unsaturated bonds like C-N or C-C triple bonds, in which stoichiometric oxidants are needed. When i...
保存先:
| 出版年: | Nat Commun |
|---|---|
| 主要な著者: | , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Nature Publishing Group UK
2019
|
| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6385223/ https://ncbi.nlm.nih.gov/pubmed/30796224 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-08849-z |
| タグ: |
タグ追加
タグなし, このレコードへの初めてのタグを付けませんか!
|