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Rhodium-Catalyzed Aldehyde Arylation via Formate-Mediated Transfer Hydrogenation: Beyond Metallic Reductants in Grignard-NHK-Type Addition
The first intermolecular carbonyl arylations via transfer hydrogenative reductive coupling are described. Using rhodium catalysts modified by (t)Bu(2)PMe, sodium formate-mediated reductive coupling of aryl iodides with aldehydes occurs in a chemoselective fashion in the presence of protic functional...
Tallennettuna:
| Julkaisussa: | J Am Chem Soc |
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| Päätekijät: | , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2019
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6376962/ https://ncbi.nlm.nih.gov/pubmed/30693768 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13652 |
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