Vinyl Triflate-Aldehyde Reductive Coupling-Redox Isomerization Mediated by Formate: Rhodium-Catalyzed Ketone Synthesis in the Absence of Stoichiometric Metals

Direct conversion of aldehydes to ketones is achieved via rhodium-catalyzed vinyl triflate-aldehyde reductive coupling-redox isomerization mediated by potassium formate. This method circumvents premetalated C-nucleophiles and discrete redox manipulations typically required to form ketones from aldeh...

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Udgivet i:Chemistry
Main Authors: Shuler, William G., Swyka, Robert A., Schempp, Tabitha T., Spinello, Brian J., Krische, Michael J.
Format: Artigo
Sprog:Inglês
Udgivet: 2019
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6763374/
https://ncbi.nlm.nih.gov/pubmed/31403727
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903668
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