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Asymmetric Allylic C–H Alkylation via Palladium (II)/cis-ArSOX Catalysis
We report the development of of Pd(II)/cis-aryl sulfoxide-oxazoline (cis-ArSOX) catalysts for asymmetric C–H alkylation of terminal olefins with a variety of synthetically versatile nucleophiles. The modular, tunable, and oxidatively stable ArSOX scaffold is key to the unprecedented broad scope and...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2018
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6370307/ https://ncbi.nlm.nih.gov/pubmed/30091907 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05668 |
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