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Palladium-Catalyzed Asymmetric Allylic Alkylations with Toluene Derivatives as Pronucleophiles
The first two highly enantioselective palladium-catalyzed allylic alkylations with benzylic nucleophiles activated with Cr(CO)(3) have been developed. These methods enable the enantioselective synthesis of “α-2-propenyl benzyl” motifs, which are important scaffolds in natural products and pharmaceut...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4836847/ https://ncbi.nlm.nih.gov/pubmed/26756125 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201509917 |
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