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Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH···F hydrogen bonding
Counterions can play an active role in chemical reactivity, modulating reaction pathways, energetics and selectivity. We investigated the tautomeric equilibrium resulting from protonation of Fe(P(Et)N(Me)P(Et))(CO)(3) (P(Et)N(Me)P(Et) = (Et(2)PCH(2))(2)NMe) at Fe or N. Protonation of Fe(P(Et)N(Me)P(...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6369578/ https://ncbi.nlm.nih.gov/pubmed/30842818 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04239j |
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