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EXCITED-STATE TWO-PROTON TAUTOMERISM IN HYDROGEN-BONDED N-HETEROCYCLIC BASE PAIRS

The optical absorption and luminescence spectra of 7-azaindole and its doubly hydrogen-bonded dimer were investigated as a model for the study of electronic interactions in DNA base pairs. It is demonstrated that a biprotonic phototautomerism occurs in the dimer and in suitable ethanol solvates in f...

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Detalhes bibliográficos
Main Authors: Taylor, Carl Al, El-Bayoumi, M. Ashraf, Kasha, Michael
Formato: Artigo
Idioma:Inglês
Publicado em: 1969
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC223555/
https://ncbi.nlm.nih.gov/pubmed/5257122
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