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EXCITED-STATE TWO-PROTON TAUTOMERISM IN HYDROGEN-BONDED N-HETEROCYCLIC BASE PAIRS
The optical absorption and luminescence spectra of 7-azaindole and its doubly hydrogen-bonded dimer were investigated as a model for the study of electronic interactions in DNA base pairs. It is demonstrated that a biprotonic phototautomerism occurs in the dimer and in suitable ethanol solvates in f...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
1969
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC223555/ https://ncbi.nlm.nih.gov/pubmed/5257122 |
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