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Hydrogen bonding vs. halogen bonding: the solvent decides

Control of intermolecular interactions is integral to harnessing self-assembly in nature. Here we demonstrate that control of the competition between hydrogen bonds and halogen bonds, the two most highly studied directional intermolecular interactions, can be exerted by choice of solvent (polarity)...

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Publicado en:Chem Sci
Autores principales: Robertson, Craig. C., Wright, James S., Carrington, Elliot J., Perutz, Robin N., Hunter, Christopher A., Brammer, Lee
Formato: Artigo
Lenguaje:Inglês
Publicado: Royal Society of Chemistry 2017
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5585772/
https://ncbi.nlm.nih.gov/pubmed/28970918
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01801k
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