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Hydrogen bonding vs. halogen bonding: the solvent decides

Control of intermolecular interactions is integral to harnessing self-assembly in nature. Here we demonstrate that control of the competition between hydrogen bonds and halogen bonds, the two most highly studied directional intermolecular interactions, can be exerted by choice of solvent (polarity)...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Robertson, Craig. C., Wright, James S., Carrington, Elliot J., Perutz, Robin N., Hunter, Christopher A., Brammer, Lee
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5585772/
https://ncbi.nlm.nih.gov/pubmed/28970918
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01801k
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