Self-complementary nickel halides enable multifaceted comparisons of intermolecular halogen bonds: fluoride ligands vs. other halides

The syntheses of three series of complexes designed with self-complementary motifs for formation of halogen bonds between an iodotetrafluorophenyl ligand and a halide ligand at square-planar nickel are reported, allowing structural comparisons of halogen bonding between all four halides C(6)F(4)I···...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Thangavadivale, Vargini, Aguiar, Pedro M., Jasim, Naseralla A., Pike, Sarah J., Smith, Dan A., Whitwood, Adrian C., Brammer, Lee, Perutz, Robin N.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2018
Pynciau:
Chemistry
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5939608/
https://ncbi.nlm.nih.gov/pubmed/29780509
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00890f
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