Self-complementary nickel halides enable multifaceted comparisons of intermolecular halogen bonds: fluoride ligands vs. other halides

The syntheses of three series of complexes designed with self-complementary motifs for formation of halogen bonds between an iodotetrafluorophenyl ligand and a halide ligand at square-planar nickel are reported, allowing structural comparisons of halogen bonding between all four halides C(6)F(4)I···...

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Udgivet i:Chem Sci
Main Authors: Thangavadivale, Vargini, Aguiar, Pedro M., Jasim, Naseralla A., Pike, Sarah J., Smith, Dan A., Whitwood, Adrian C., Brammer, Lee, Perutz, Robin N.
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2018
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5939608/
https://ncbi.nlm.nih.gov/pubmed/29780509
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00890f
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