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Hydrogen bonding vs. halogen bonding: the solvent decides

Control of intermolecular interactions is integral to harnessing self-assembly in nature. Here we demonstrate that control of the competition between hydrogen bonds and halogen bonds, the two most highly studied directional intermolecular interactions, can be exerted by choice of solvent (polarity)...

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Pubblicato in:Chem Sci
Autori principali: Robertson, Craig. C., Wright, James S., Carrington, Elliot J., Perutz, Robin N., Hunter, Christopher A., Brammer, Lee
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2017
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5585772/
https://ncbi.nlm.nih.gov/pubmed/28970918
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01801k
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