Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt

Rare mono- and diorganopentaphosphido cobalt complexes are accessible by P–P condensation using the unprecedented, reactive cobalt-gallium tetraphosphido complex [K(dme)(2){((Mes)BIAN)Co(μ-η(4):η(2)-P(4))Ga(nacnac)}] (2). Compound 2 was prepared in good yield by reaction of [K(Et(2)O){((Mes)BIAN)Co(...

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Vydáno v:Chem Sci
Hlavní autoři: Ziegler, Christoph G. P., Maier, Thomas M., Pelties, Stefan, Taube, Clemens, Hennersdorf, Felix, Ehlers, Andreas W., Weigand, Jan J., Wolf, Robert
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2018
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6357856/
https://ncbi.nlm.nih.gov/pubmed/30809344
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04745f
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