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Synthesis of N-Heterocycle Substituted Silyl Ligands within the Coordination Sphere of Iron

[Image: see text] N-Heterocycle-substituted silyl iron complexes have been synthesized by nucleophilic substitution at trichlorosilyl ligands bound to iron. The homoleptic (tripyrrolyl)- and tris(3-methylindolyl)silyl groups were accessed from (Cl(3)Si)CpFe(CO)(2) (Cl(3)SiFp) by substitution of chlo...

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Bibliografiske detaljer
Udgivet i:Organometallics
Main Authors: Witteman, Léon, Lutz, Martin, Moret, Marc-Etienne
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2018
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6158677/
https://ncbi.nlm.nih.gov/pubmed/30270963
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.8b00399
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