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A Free Silanide from Nucleophilic Substitution at Silicon(II)
A computationally guided synthetic route to a free silanide derived from tris(3‐methylindol‐2‐yl)methane ([(tmim)Si](−)) through nucleophilic substitution on the Si(II) precursor (Idipp)SiCl(2) is reported (Idipp=2,3‐dihydro‐1,3‐bis(2,6‐diisopropylphenyl)‐1H‐imidazol‐2‐ylidene). This approach circum...
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| Gepubliceerd in: | Chemistry |
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| Hoofdauteurs: | , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2018
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6120461/ https://ncbi.nlm.nih.gov/pubmed/29577491 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201801435 |
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