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Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt
Rare mono- and diorganopentaphosphido cobalt complexes are accessible by P–P condensation using the unprecedented, reactive cobalt-gallium tetraphosphido complex [K(dme)(2){((Mes)BIAN)Co(μ-η(4):η(2)-P(4))Ga(nacnac)}] (2). Compound 2 was prepared in good yield by reaction of [K(Et(2)O){((Mes)BIAN)Co(...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6357856/ https://ncbi.nlm.nih.gov/pubmed/30809344 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04745f |
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