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[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide

The activation of white phosphorus (P(4)) by transition‐metal complexes has been studied for several decades, but the functionalization and release of the resulting (organo)phosphorus ligands has rarely been achieved. Herein we describe the formation of rare diphosphan‐1‐ide anions from a P(5) ligan...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Hoidn, Christian M., Maier, Thomas M., Trabitsch, Karolina, Weigand, Jan J., Wolf, Robert
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972699/
https://ncbi.nlm.nih.gov/pubmed/31573718
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908744
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