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[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide

The activation of white phosphorus (P(4)) by transition‐metal complexes has been studied for several decades, but the functionalization and release of the resulting (organo)phosphorus ligands has rarely been achieved. Herein we describe the formation of rare diphosphan‐1‐ide anions from a P(5) ligan...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Hoidn, Christian M., Maier, Thomas M., Trabitsch, Karolina, Weigand, Jan J., Wolf, Robert
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972699/
https://ncbi.nlm.nih.gov/pubmed/31573718
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908744
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