Sodium-coupled electron transfer reactivity of metal–organic frameworks containing titanium clusters: the importance of cations in redox chemistry

Stoichiometric reduction reactions of two metal–organic frameworks (MOFs) by the solution reagents [Image: see text] (M = Cr, Co) are described. The two MOFs contain clusters with Ti(8)O(8) rings: Ti(8)O(8)(OH)(4)(bdc)(6); bdc = terephthalate (MIL-125) and Ti(8)O(8)(OH)(4)(bdc-NH(2))(6); bdc-NH(2) =...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Saouma, Caroline T., Tsou, Chih-Chin, Richard, Sarah, Ameloot, Rob, Vermoortele, Frederik, Smolders, Simon, Bueken, Bart, DiPasquale, Antonio G., Kaminsky, Werner, Valdez, Carolyn N., De Vos, Dirk E., Mayer, James M.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2018
Teme:
Chemistry
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6354900/
https://ncbi.nlm.nih.gov/pubmed/30809347
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04138e
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