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Protonation and Concerted Proton-Electron Transfer Reactivity of a Bis-Benzimidazolate Ligated [2Fe-2S] Model for Rieske Clusters
A model system for biological Rieske clusters that incorporates bis-benzimidazolate ligands ((Pr)bbim)(2-) has been developed ((Pr)bbimH(2) = 4,4-bis(benzimidazol-2-yl)heptane). The di-ferric and mixed-valence clusters have been prepared and characterized in both their protonated and deprotonated st...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3342399/ https://ncbi.nlm.nih.gov/pubmed/22519585 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3019324 |
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