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Protonation and Concerted Proton-Electron Transfer Reactivity of a Bis-Benzimidazolate Ligated [2Fe-2S] Model for Rieske Clusters

A model system for biological Rieske clusters that incorporates bis-benzimidazolate ligands ((Pr)bbim)(2-) has been developed ((Pr)bbimH(2) = 4,4-bis(benzimidazol-2-yl)heptane). The di-ferric and mixed-valence clusters have been prepared and characterized in both their protonated and deprotonated st...

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Bibliografski detalji
Glavni autori: Saouma, Caroline T., Kaminsky, Werner, Mayer, James M.
Format: Artigo
Jezik:Inglês
Izdano: 2012
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3342399/
https://ncbi.nlm.nih.gov/pubmed/22519585
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3019324
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