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Protonation and Proton-Coupled Electron Transfer at S-Ligated [4Fe-4S] Clusters
Biological [Fe-S] clusters are increasingly recognized to undergo proton-coupled electron transfer (PCET), but the site of protonation, mechanism, and role for PCET remains largely unknown. Here we explore this reactivity with synthetic model clusters. Protonation of the arylthiolate-ligated [4Fe-4S...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4646712/ https://ncbi.nlm.nih.gov/pubmed/25965413 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201500152 |
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