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Fast Proton-Coupled Electron Transfer Observed for a High-Fidelity Structural and Functional [2Fe–2S] Rieske Model

[Image: see text] Rieske cofactors have a [2Fe–2S] cluster with unique {His(2)Cys(2)} ligation and distinct Fe subsites. The histidine ligands are functionally relevant, since they allow for coupling of electron and proton transfer (PCET) during quinol oxidation in respiratory and photosynthetic ET...

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Detalhes bibliográficos
Main Authors: Albers, Antonia, Demeshko, Serhiy, Dechert, Sebastian, Saouma, Caroline T., Mayer, James M., Meyer, Franc
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985845/
https://ncbi.nlm.nih.gov/pubmed/24506804
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja412449v
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