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Sodium-coupled electron transfer reactivity of metal–organic frameworks containing titanium clusters: the importance of cations in redox chemistry
Stoichiometric reduction reactions of two metal–organic frameworks (MOFs) by the solution reagents [Image: see text] (M = Cr, Co) are described. The two MOFs contain clusters with Ti(8)O(8) rings: Ti(8)O(8)(OH)(4)(bdc)(6); bdc = terephthalate (MIL-125) and Ti(8)O(8)(OH)(4)(bdc-NH(2))(6); bdc-NH(2) =...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , , , , , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Royal Society of Chemistry
2018
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| 主題: | |
| オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6354900/ https://ncbi.nlm.nih.gov/pubmed/30809347 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04138e |
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