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Computational characterization of enzyme-bound thiamin diphosphate reveals a surprisingly stable tricyclic state: implications for catalysis

Thiamin diphosphate (ThDP)-dependent enzymes constitute a large class of enzymes that catalyze a diverse range of reactions. Many are involved in stereospecific carbon–carbon bond formation and, consequently, have found increasing interest and utility as chiral catalysts in various biocatalytic appl...

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Bibliografiske detaljer
Udgivet i:Beilstein J Org Chem
Main Authors: Planas, Ferran, McLeish, Michael J, Himo, Fahmi
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6350894/
https://ncbi.nlm.nih.gov/pubmed/30745990
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.15
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