Sesquiterpene Synthase‐Catalysed Formation of a New Medium‐Sized Cyclic Terpenoid Ether from Farnesyl Diphosphate Analogues

Terpene synthases catalyse the first step in the conversion of prenyl diphosphates to terpenoids. They act as templates for their substrates to generate a reactive conformation, from which a Mg(2+)‐dependent reaction creates a carbocation–PP(i) ion pair that undergoes a series of rearrangements and...

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Vydáno v:Chembiochem
Hlavní autoři: Huynh, Florence, Grundy, Daniel J., Jenkins, Robert L., Miller, David J., Allemann, Rudolf K.
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2018
Témata:
Communications
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6334173/
https://ncbi.nlm.nih.gov/pubmed/29802753
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cbic.201800218
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