In crystallo thermodynamic analysis of conformational change of the topaquinone cofactor in bacterial copper amine oxidase

In the catalytic reaction of copper amine oxidase, the protein-derived redox cofactor topaquinone (TPQ) is reduced by an amine substrate to an aminoresorcinol form (TPQ(amr)), which is in equilibrium with a semiquinone radical (TPQ(sq)). The transition from TPQ(amr) to TPQ(sq) is an endothermic proc...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Murakawa, Takeshi, Baba, Seiki, Kawano, Yoshiaki, Hayashi, Hideyuki, Yano, Takato, Kumasaka, Takashi, Yamamoto, Masaki, Tanizawa, Katsuyuki, Okajima, Toshihide
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2019
Assuntos:
Biological Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6320532/
https://ncbi.nlm.nih.gov/pubmed/30563857
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1811837116
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