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Thermodynamics and Kinetics of Guest-Induced Switching between “Basket Handle” Porphyrin Isomers

The synthesis and switching properties of two “basket handle” porphyrin isomers is described. The cis-oriented meso-phenyl groups of these porphyrins are linked at their ortho-positons via benzocrown-ether-based spacers, which as a result of slow atropisomerization are located either on the same sid...

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Publicado en:Molecules
Autores principales: Deutman, Alexander B. C., Woltinge, Tim, Smits, Jan M. M., Gelder, René De, Elemans, Johannes A. A. W., Nolte, Roeland J. M., Rowan, Alan E.
Formato: Artigo
Lenguaje:Inglês
Publicado: MDPI 2014
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6271905/
https://ncbi.nlm.nih.gov/pubmed/24762966
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules19045278
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