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Theoretical Analysis on the Kinetic Isotope Effects of Bimolecular Nucleophilic Substitution (S(N)2) Reactions and Their Temperature Dependence
Factors affecting the kinetic isotope effects (KIEs) of the gas-phase S(N)2 reactions and their temperature dependence have been analyzed using the ion-molecule collision theory and the transition state theory (TST). The quantum-mechanical tunneling effects were also considered using the canonical v...
Zapisane w:
| Wydane w: | Molecules |
|---|---|
| Główni autorzy: | , |
| Format: | Artigo |
| Język: | Inglês |
| Wydane: |
MDPI
2013
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| Hasła przedmiotowe: | |
| Dostęp online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6270110/ https://ncbi.nlm.nih.gov/pubmed/23612475 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules18044816 |
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