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Theoretical Analysis of Kinetic Isotope Effects on Proton Transfer Reactions between Substituted α-Methoxystyrenes and Substituted Acetic Acids

Primary kinetic isotope effects (KIEs) on a series of carboxylic acid-catalyzed protonation reactions of aryl-substituted α-methoxystyrenes (X-1) to form oxocarbenium ions have been computed using the Kleinert variational second-order perturbation theory (KP2) in the framework of Feynman path integr...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Wong, Kin Yiu, Richard, John P., Gao, Jiali
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2009
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2759073/
https://ncbi.nlm.nih.gov/pubmed/19754046
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja905081x
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