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A Marcus Treatment of Rate Constants for Protonation of Ring-Substituted α-Methoxystyrenes: Intrinsic Reaction Barriers and the Shape of the Reaction Coordinate
Rate and equilibrium constants were determined for protonation of ring-substituted α-methoxystyrenes by hydronium ion and by carboxylic acids to form the corresponding ring-substituted α-methyl α-methoxybenzyl carbocations at 25 ° C and I = 1.0 (KCl). The thermodynamic barrier to carbocation formati...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2007
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2615229/ https://ncbi.nlm.nih.gov/pubmed/17488079 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja071007k |
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