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Combined QM/MM and Path Integral Simulations of Kinetic Isotope Effects in the Proton Transfer Reaction Between Nitroethane and Acetate Ion in Water

An integrated Feynman path integral-free energy perturbation and umbrella sampling (PI-FEP/UM) method has been used to investigate the kinetic isotope effects (KIEs) in the proton transfer reaction between nitroethane and acetate ion in water. In the present study, both nuclear and electronic quantu...

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Bibliografski detalji
Glavni autori: GAO, JIALI, WONG, KIN-YIU, MAJOR, DAN T.
Format: Artigo
Jezik:Inglês
Izdano: 2008
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2827405/
https://ncbi.nlm.nih.gov/pubmed/17722009
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/jcc.20810
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