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Two-Carbon Homologation of Aldehydes and Ketones to α,β-Unsaturated Aldehydes

Phosphonate reagents were developed for the two-carbon homologation of aldehydes or ketones to unbranched- or methyl-branched α,β-unsaturated aldehydes. The phosphonate reagents, diethyl methylformyl-2-phosphonate dimethylhydrazone and diethyl ethylformyl-2-phosphonate dimethylhydrazone, contained a...

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Publicat a:Molecules
Autors principals: Petroski, Richard J., Vermillion, Karl, Cossé, Allard A.
Format: Artigo
Idioma:Inglês
Publicat: MDPI 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6264399/
https://ncbi.nlm.nih.gov/pubmed/21694671
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules16065062
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