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Understanding Biological Hydrogen Transfer Through the Lens of Temperature Dependent Kinetic Isotope Effects
Hydrogen atom transfer (HAT) is a salient feature of many enzymatic C-H cleavage mechanisms. In systems where kinetic isolation of HAT is achieved, selective labelling of substrate with hydrogen isotopes, such as deuterium, enables the determination of intrinsic kinetic isotope effects (KIEs). While...
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| Pubblicato in: | Acc Chem Res |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2018
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6258190/ https://ncbi.nlm.nih.gov/pubmed/30152685 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.8b00226 |
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