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Total Synthesis Establishes the Biosynthetic Pathway to the Naphterpin and Marinone Natural Products
The naphterpins and marinones are naphthoquinone meroterpenoids with an unusual aromatic oxidation pattern that is biosynthesized from 1,3,6,8-tetrahydroxynaphthalene (THN). We propose that cryptic halogenation of THN derivatives by vanadium-dependent chloroperoxidase (VCPO) enzymes is key to this b...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6248334/ https://ncbi.nlm.nih.gov/pubmed/29935040 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201804351 |
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