Crystallographic and spectroscopic assignment of the proton transfer pathway in [FeFe]-hydrogenases

The unmatched catalytic turnover rates of [FeFe]-hydrogenases require an exceptionally efficient proton-transfer (PT) pathway to shuttle protons as substrates or products between bulk water and catalytic center. For clostridial [FeFe]-hydrogenase CpI such a pathway has been proposed and analyzed, bu...

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Argitaratua izan da:Nat Commun
Egile Nagusiak: Duan, Jifu, Senger, Moritz, Esselborn, Julian, Engelbrecht, Vera, Wittkamp, Florian, Apfel, Ulf-Peter, Hofmann, Eckhard, Stripp, Sven T., Happe, Thomas, Winkler, Martin
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Nature Publishing Group UK 2018
Gaiak:
Article
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6226526/
https://ncbi.nlm.nih.gov/pubmed/30413719
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-07140-x
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