A structural view of synthetic cofactor integration into [FeFe]-hydrogenases

[FeFe]-hydrogenases are nature's fastest catalysts for the evolution or oxidation of hydrogen. Numerous synthetic model complexes for the [2Fe] subcluster (2Fe(H)) of their active site are known, but so far none of these could compete with the enzymes. The complex Fe(2)[μ-(SCH(2))(2)X](CN)(2)(C...

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Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Esselborn, J., Muraki, N., Klein, K., Engelbrecht, V., Metzler-Nolte, N., Apfel, U.-P., Hofmann, E., Kurisu, G., Happe, T.
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2016
Teme:
Chemistry
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5954619/
https://ncbi.nlm.nih.gov/pubmed/29896366
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03397g
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