Spectroscopical Investigations on the Redox Chemistry of [FeFe]-Hydrogenases in the Presence of Carbon Monoxide

[FeFe]-hydrogenases efficiently catalyzes hydrogen conversion at a unique [4Fe–4S]-[FeFe] cofactor, the so-called H-cluster. The catalytic reaction occurs at the diiron site, while the [4Fe–4S] cluster functions as a redox shuttle. In the oxidized resting state (Hox), the iron ions of the diiron sit...

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Bibliografske podrobnosti
izdano v:Molecules
Main Authors: Laun, Konstantin, Mebs, Stefan, Duan, Jifu, Wittkamp, Florian, Apfel, Ulf-Peter, Happe, Thomas, Winkler, Martin, Haumann, Michael, Stripp, Sven T.
Format: Artigo
Jezik:Inglês
Izdano: MDPI 2018
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Article
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6100070/
https://ncbi.nlm.nih.gov/pubmed/29987246
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules23071669
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