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An enantioselective synthesis of the C(1)–C(9) segment of antitumor macrolide peloruside A
A stereocontrolled synthesis of the C(1)–C(9) segment of the marine natural product peloruside A is described. The key steps involve Sharpless’s catalytic asymmetric dihydroxylation reaction, a chelation-controlled reduction of chiral β-alkoxy ketones to elaborate the syn-1,3-diol functionality and...
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| Publicat a: | Tetrahedron Lett |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2003
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6214207/ https://ncbi.nlm.nih.gov/pubmed/30393410 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/S0040-4039(03)00744-5 |
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