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Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene–Imine [3 + 2] Annulation
We have prepared a previously unreported family of P-stereogenic [2.2.1] bicyclic chiral phosphines through straightforward syntheses starting from the natural product carvone. This design rationale prompted the development of an unforeseen C-dealkenylation reaction. We have applied these organocata...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | ACS Catal |
|---|---|
| Prif Awduron: | , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2018
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6208446/ https://ncbi.nlm.nih.gov/pubmed/30393576 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b01081 |
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