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Phosphine-Initiated General Base Catalysis: Facile Access to Benzannulated 1,3-Diheteroatom Five-Membered Rings via Double-Michael Reactions of Allenes

[Image: see text] General base-catalyzed double-Michael reactions of allenes with various dinucleophiles are described. The reactions are facilitated most efficiently by a catalytic amount of trimethylphosphine, affording six types of C2-functionalized benzannulated five-membered heterocycles: benzi...

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Hlavní autoři: Szeto, Judy, Sriramurthy, Vardhineedi, Kwon, Ohyun
Médium: Artigo
Jazyk:Inglês
Vydáno: 2011
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3193576/
https://ncbi.nlm.nih.gov/pubmed/21932819
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201730q
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