Transition metal-free direct dehydrogenative arylation of activated C(sp(3))–H bonds: synthetic ambit and DFT reactivity predictions

A transition metal-free dehydrogenative method for the direct mono-arylation of a wide range of activated C(sp(3))–H bonds has been developed. This operationally simple and environmentally friendly aerobic arylation uses tert-BuOK as the base and nitroarenes as electrophiles to prepare up to gram qu...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Lovato, Kaitlyn, Guo, Lirong, Xu, Qing-Long, Liu, Fengting, Yousufuddin, Muhammed, Ess, Daniel H., Kürti, László, Gao, Hongyin
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6202766/
https://ncbi.nlm.nih.gov/pubmed/30450183
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02758g
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