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Transition metal-free direct dehydrogenative arylation of activated C(sp(3))–H bonds: synthetic ambit and DFT reactivity predictions
A transition metal-free dehydrogenative method for the direct mono-arylation of a wide range of activated C(sp(3))–H bonds has been developed. This operationally simple and environmentally friendly aerobic arylation uses tert-BuOK as the base and nitroarenes as electrophiles to prepare up to gram qu...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2018
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6202766/ https://ncbi.nlm.nih.gov/pubmed/30450183 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02758g |
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