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Pyridine-enabled copper-promoted cross dehydrogenative coupling of C(sp(2))–H and unactivated C(sp(3))–H bonds

The pyridine-enabled cross dehydrogenative coupling of sp(2) C–H bonds of polyfluoroarenes and unactivated sp(3) C–H bonds of amides was achieved via a copper-promoted process with good functional group compatibility. This reaction showed great site-selectivity by favoring the sp(2) C–H bonds ortho...

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Pubblicato in:Chem Sci
Autori principali: Wu, Xuesong, Zhao, Yan, Ge, Haibo
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5950755/
https://ncbi.nlm.nih.gov/pubmed/29861919
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02143j
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