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Selective Conversion of CO(2) to Isocyanate by Low–Coordinate Fe
Discovery of the mechanisms for selective transformations of CO(2) into organic compounds is a challenge. Here, we describe the reaction of low-coordinate Fe silylamide complexes with CO(2) to give trimethylsilyl isocyanate and the corresponding Fe siloxide complex. Kinetic studies show that this is...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2018
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6151862/ https://ncbi.nlm.nih.gov/pubmed/29633494 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802357 |
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