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Selective Conversion of CO(2) to Isocyanate by Low–Coordinate Fe
Discovery of the mechanisms for selective transformations of CO(2) into organic compounds is a challenge. Here, we describe the reaction of low-coordinate Fe silylamide complexes with CO(2) to give trimethylsilyl isocyanate and the corresponding Fe siloxide complex. Kinetic studies show that this is...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6151862/ https://ncbi.nlm.nih.gov/pubmed/29633494 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802357 |
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