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Selective Conversion of CO(2) to Isocyanate by Low–Coordinate Fe

Discovery of the mechanisms for selective transformations of CO(2) into organic compounds is a challenge. Here, we describe the reaction of low-coordinate Fe silylamide complexes with CO(2) to give trimethylsilyl isocyanate and the corresponding Fe siloxide complex. Kinetic studies show that this is...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Broere, Daniёl L. J., Mercado, Brandon Q., Holland, Patrick L.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6151862/
https://ncbi.nlm.nih.gov/pubmed/29633494
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802357
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