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Synthesis of N–H Bearing Imidazolidinones and Dihydroimidazolones Using Aza-Heck Cyclizations

The synthesis of unsaturated, unprotected imidazolidinones via an aza-Heck reaction is described. This palladium-catalyzed process allows for the cyclization of N-phenoxy ureas onto pendant alkenes. The reaction has broad functional group tolerance, can be applied to complex ring topologies, and can...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Xu, Feiyang, Shuler, Scott A., Watson, Donald A.
Format: Artigo
Langue:Inglês
Publié: 2018
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6141047/
https://ncbi.nlm.nih.gov/pubmed/30125443
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201806295
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